Page 10 - Synthesis of Functional Nanoparticles Using an Atmospheric Pressure Microplasma Process - LiangLiang Lin
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4.
3.3.1 Imaging of the Microdischarge in Argon with and without Precursor Admixture............44 3.3.2 OES of Microplasma Reactor ............................................................................................ 45 3.3.3 SEM and EDX Analysis...................................................................................................... 47 3.3.4 TEM Analysis ..................................................................................................................... 48 3.3.5 XRD Measurements............................................................................................................ 50 3.3.6 XPS Results ........................................................................................................................ 51
3.4 Mechanism Study .......................................................................................................52
3.4.1 Microplasma Parameters................................................................................................... 52 3.4.2 Metal-cyclopentadienyl Dissociation Stage....................................................................... 54 3.4.3 Cyclopentadienyl Ring Dissociation Stage ........................................................................ 55
3.5 Conclusions ................................................................................................................56 Reference..........................................................................................................................56
Titanium Nitride Nanoparticles Synthesis - an Advanced Model Study towards Nitride Nanomaterials................................................................................................59
4.1 Introduction ................................................................................................................60 4.2 Experiment Section ....................................................................................................61 4.2.1 Experimental ...................................................................................................................... 61 4.2.2 Characterization ................................................................................................................ 62
4.3 Results and Discussion...............................................................................................62
4.3.1 Electrical Characterization of the Microplasma during TiN Synthesis Process ............... 62 4.3.2 Optical Emission Studies of the Precursor Dissociation Process ..................................... 63 4.3.3 Synthesis of Titanium Nitride Nanoparticles ..................................................................... 65
4.4 Process Analysis and Discussion................................................................................69 4.5 Conclusions ................................................................................................................74 References ........................................................................................................................74
Solvent-Free Nickel Nanoparticles Synthesis and Engineering –Controllable Magnetic Properties ...................................................................................................77
5.1 Introduction ................................................................................................................78 5.2 Experiment Section ....................................................................................................79 5.2.1 Experimental ...................................................................................................................... 79 5.2.2 Characterization ................................................................................................................ 81
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